(d) Assertion (A) is false, but Reason (R) is true.
The correct practice is to add acid to water (not water to acid). So Assertion (A) is false. The Reason (R) is true — dissolving acid in water is highly exothermic.
The textbook (Chapter 2, Activity 2.10) clearly states: "The acid must always be added slowly to water with constant stirring." The Assertion incorrectly reverses this — it says "add water to acid," which is the dangerous practice. The Reason is correctly stated (the process is highly exothermic). Hence, A is false but R is true → option (d).