(d) Na₂CO₃
Na₂CO₃·10H₂O (washing soda) has 10 water molecules of crystallisation, which is the maximum among the given compounds (FeSO₄·7H₂O, CuSO₄·5H₂O, CaSO₄·2H₂O).
Source: Chapter 2, Section 2.4.4
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The water of crystallisation for each compound:
The textbook explicitly states Na₂CO₃·10H₂O (washing soda). Note: FeSO₄·7H₂O is not mentioned in the passage but is standard NCERT knowledge; Na₂CO₃ with 10 water molecules is the clear winner. Always remember the formula of washing soda for board exams.