(D) CH₄ + 2O₂ ⎯⎯→ CO₂ + 2H₂O + Energy
The equation must be balanced (2O₂ on LHS; 1C, 4H, 4O on each side) and show energy released (exothermic). Option A is unbalanced; B has wrong products (2CO₂); C is balanced but missing energy. Only D is both correctly balanced and shows energy as a product of this exothermic combustion reaction.