(a) Metals in the middle of the reactivity series (e.g., iron, copper) can be extracted using displacement reactions where a more reactive metal displaces them from their salt solutions.
Example 1: $\text{Fe}_2\text{O}_3 + 2\text{Al} \rightarrow \text{Al}_2\text{O}_3 + 2\text{Fe}$
(Aluminium displaces iron from iron oxide — thermite reaction)
Example 2: $\text{CuSO}_4(aq) + \text{Fe}(s) \rightarrow \text{FeSO}_4(aq) + \text{Cu}(s)$
(Iron displaces copper from copper sulphate solution)
(b) Metals high up in the reactivity series (e.g., Na, K, Ca, Al) are very reactive and have a stronger affinity for oxygen than carbon does. Carbon cannot reduce their oxides because it is less reactive than these metals, so carbon reduction fails.
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