AI-generated practice question — model-generated for extra practice, not a previous-year CBSE board question.
Although saturated hydrocarbons are generally inert to most reagents, they can still undergo substitution reactions under specific conditions. In this reaction, a chlorine atom replaces one hydrogen atom of methane to form chloromethane (CH₃Cl) and HCl.
Sunlight is essential because it provides the energy needed to activate the chlorine molecules (Cl₂), enabling the reaction to proceed. Without sunlight, the activation energy is not supplied, so the reaction does not occur. This is why the same mixture of methane and chlorine shows no reaction in the dark.
$$\text{CH}_4 + \text{Cl}_2 \xrightarrow{\text{sunlight}} \text{CH}_3\text{Cl} + \text{HCl}$$
Source: Chapter 4, Section 4.3.4 – Substitution Reaction
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